Publications

2021


55) "Chiral distorted hexa-peri-hexabenzocoronenes bearing a nonagon-embedded carbohelicene" image

M. A. Medel, C. M. Cruz, D. Miguel, V. Blanco, S. P. Morcillo, A. G. Campaña.
Angew. Chem. Int. Ed., 2021, 60, 22051-22056

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54) "Three-state molecular potentiometer based on a non-symmetrically positioned in-backbone linker"

L. Palomino-Ruiz, P. Reiné, I. R. Márquez, L. Álvarez de Cienfuegos, N. Agraït,J. M. Cuerva, A. G. Campaña, E. Leary, D. Miguel, A. Millán, L. A. Zotti, M. T. González.
J. Mater. Chem. C, 2021, 9, 16282-16289

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53) "Bright Long‐Lived Circularly Polarized Luminescence in Chiral Chromium(III) Complexes"

J.‐R. Jiménez, M. Poncet, S. Míguez‐Lago, S. Grass, J. Lacour, C. Besnard, J. M. Cuerva, A. G. Campaña, C. Piguet.
Angew. Chem. Int. Ed., 2021, 60, 10095-10102
Article featured as Back Cover in Angewandte Chemie International Edition

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52) "Octagon‐embedded carbohelicene as chiral motif for CPL emission of saddle‐helix nanographenes"

M. A. Medel, R. Tapia, V. Blanco, D. Miguel, S. P. Morcillo, A. G. Campaña.
Angew. Chem. Int. Ed., 2021, 60, 6094-6100
Article highlighted as Hot Paper.

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51) "Single‐Molecule Conductance of 1,4‐Azaborine Derivatives as Models of BN‐doped PAHs"

L. Palomino-Ruiz, S. Rodríguez-González, J. G. Fallaque, I. R. Márquez, N. Agraït, C. Díaz, E. Leary, J. M. Cuerva, A. G. Campaña, F. Martín, A. Millán, M. T. Gonzalez.
Angew. Chem. Int. Ed., 2021, 60, 6609-6616

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50) "Heptagon-Containing Saddle-Shaped Nanographenes: Self-Association and Complexation Studies with Polycyclic Aromatic Hydrocarbons and Fullerenes" image

A. H. G. David, S. Míguez-Lago, C. M. Cruz, J. M. Cuerva, V. Blanco, A. G. Campaña.
Organic Materials, 2021, 3, 51-59
Article highlighted in the Focus Issue Curved Organic π-Systems .

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2020


49) "Dibenzocycloheptatriene as end-group of Thiele and tetrabenzo-Chichibabin hydrocarbons" image

V. G. Jiménez, P. Mayorga Burrezo, V. Blanco, V. Lloveras, C. J. Gomez Garcia, T. Šolomek J. M. Cuerva, J. Veciana, A. G. Campaña.
Chem. Commun., 2020, 56, 12813-12816

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48) "Nanografenos imperfectos: perfectos en la búsqueda de nuevas propiedades quirópticas"

S. Míguez-Lago, A. G. Campaña.
An. Quím., 2020, 116, 132-145
Article featured as Cover in Anales de Química

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47) "A Macrocycle Based on a Heptagon‐Containing Hexa‐peri‐hexabenzocoronene" image

V. G. Jiménez, A. H. G. David, J. M. Cuerva, V. Blanco, A. G. Campaña.
Angew. Chem. Int. Ed., 2020, 59, 15124-15128
Article highlighted as Hot Paper.

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46) "Two‐photon absorption enhancement by the inclusion of a tropone ring in distorted nanographene ribbons" image

S. Castro-Fernández, C. M. Cruz, I. F. A. Mariz, I. R. Márquez, V. G. Jiménez, L. Palomino-Ruiz, J. M. Cuerva, E. Maçôas, A. G. Campaña.
Angew. Chem. Int. Ed., 2020, 59, 7139-7145
Article highlighted in the collection: Hot topic: Carbon, Graphite, and Graphene from Advanced Materials
Article highlighted in Chemistry Views: Distorted Nanographene Ribbons .
Article featured as Inside Back Cover in Angewandte Chemie International Edition

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45) "Simple perylene diimide cyclohexane derivative with combined CPL and TPA properties" image

P. Reiné, A. M. Ortuño, I. Mariz, M. Ribagorda, J. M. Cuerva, A. G. Campaña, E. Maçôas, D. Miguel.
Front. Chem., 2020, 8, 306.

44) "An enantiopure propeller‐like trityl‐brominated radical: Bringing together a high racemization barrier and an efficient circularly polarized luminescent magnetic emitter" image

P. Mayorga-Burrezo, V. G. Jiménez, D. Blasi, T. Parella, I. Ratera, A. G. Campaña, J. Veciana.
Chem. Eur. J., 2020, 26, 3776-3781.
Article highlighted in Chemistry Views and featured as Cover Feature in Chemistry - A European Journal

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2019


43) "A [2]Rotaxane-Based Circularly Polarized Luminescence Switch" image

A. H. G. David, R. Casares, J. M. Cuerva, A. G. Campaña, V. Blanco
J. Am. Chem. Soc., 2019, 141, 18064-18074.

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42) "Organic free radicals as circularly polarized luminescence" image

P. Mayorga Burrezo, V. G. Jiménez, D. Blasi, I. Ratera, A. G. Campaña, J. Veciana
Angew. Chem. Int. Ed., 2019, 58, 16282-16288.

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41) "Chiral double stapled o-OPEs with intense circularly polarized luminescence"

P. Reiné, A. G. Campaña, L. Álvarez de Cienfuegos, V. Blanco, S. Abbate, A. J. Mota, G. Longhi, D. Miguel, J. M. Cuerva.
Chem. Commun., 2019, 55, 10685-10688.

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40) "Chiral Molecular Ruby [Cr(dqp)2]3+ with Long-Lived Circularly Polarized Luminescence"

J.-R. Jiménez, B. Doistau, C. M. Cruz, C. Besnard, J. M. Cuerva, A. G. Campaña, C. Piguet.
J. Am. Chem. Soc., 2019, 141, 13244-13252.

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39) "A triskelion-shaped saddle-helix hybrid nanographene" image

C. M. Cruz, I. R. Márquez, S. Castro-Fernández, J. M. Cuerva, E. Maçôas, A. G. Campaña
Angew. Chem. Int. Ed., 2019, 58, 8068-8072.

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38) "Combining Defects in a Single Nanographene: A Fully Helical Saddle Ribbon" image

C. M. Cruz, S. Castro-Fernández, E. Maçôas, A. Millán, A. G. Campaña
Synlett, 2019, 30, 997-1002.
Article highlited on the front cover of Synlett.

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37) "[2]Rotaxane End-Capping Synthesis by Click Michael-Type Addition to the Vinyl Sulfonyl Group"

A. H. G. David, P. García-Cerezo, A. G. Campaña, F. Santoyo-González, V. Blanco
Chem. Eur. J., 2019, 25, 6170-6179.

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36) "O–H and (CO)N–H bond weakening by coordination to Fe(II)"

S. Resa, A. Millán, N. Fuentes, L. Crovetto, M. L. Marcos, L. Lezama, D. Choquesillo-Lazarte, V. Blanco, A. G. Campaña, D. J. Cárdenas, J. M. Cuerva
Dalton Trans., 2019, 48, 2179-2189.

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2018


35) "OFF/ON switching of circularly polarized luminescence by oxophilic interaction of homochiral sulfoxide-containing o-OPEs with metal cations"

P. Reiné, A. M. Ortuño, S. Resa, L. Álvarez de Cienfuegos, V. Blanco, M. J. Ruedas-Rama, G. Mazzeo, S. Abbate, A. Lucotti, M. Tommasini, S. Guisán-Ceinos, M. Ribagorda, A. G. Campaña, A. Mota, G. Longhi, D. Miguel and J. M. Cuerva
Chem. Commun., 2018, 54, 13985-13988.

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34) "Circularly Polarized Luminescence of Boronic Acid-Derived Salicylidenehydrazone Complexes Containing Chiral Boron as Stereogenic Unit" image

V. G. Jiménez, F. M. F. Santos, S. Castro-Fernández, J. M. Cuerva, P. M. P. Gois, U. Pischel and A. G. Campaña
J. Org. Chem., 2018, 83, 22, 14057-14062.

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33) "Undecabenzo[7]superhelicene: A Helical Nanographene Ribbon as a Circularly Polarized Luminescence Emitter" image

C. M. Cruz, S. Castro-Fernández, E. Maçôas, J. M. Cuerva and A. G. Campaña
Angew. Chem. Int. Ed., 2018, 57, 14782-14786.
Article highlighted as Very Important Paper.

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32) "Synthesis of distorted nanographenes containing seven- and eight-membered carbocycles" image

I. R. Márquez, S. Castro-Fernández, A. Millán and A. G. Campaña
Chem. Commun., 2018, 54, 6705-6718.

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31) "Pyrene-Containing ortho-Oligo(phenylene)ethynylene Foldamer as a Ratiometric Probe Based on Circularly Polarized Luminescence"

P. Reiné, J. Justicia, S. P. Morcillo, S. Abbate , B. Vaz, M. Ribagorda , Á. Orte , L. Álvarez de Cienfuegos, G. Longhi, A. G. Campaña, D. Miguel, and J. M. Cuerva
J. Org. Chem., 2018, 83, 4455-4463.image
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30) "Enantiopure distorted ribbon-shaped nanographene combining two-photon absorption-based image upconversion and circularly polarized luminescence”

C. M. Cruz, I. R. Márquez, I. F. A. Mariz, V. Blanco, C. Sánchez-Sánchez, J. M. Sobrado, J. A. Martín-Gago, J. M. Cuerva, E. Maçôas and A. G. Campaña
Chem. Sci., 2018, 9, 3917-3924.
This article was selected among the Most Impactful Nanoscience Articles published in Chemical Science

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This article has been featured on the INSIDE BACK COVER of Chemical Science.

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29) "Aggregation-induced emission of [3]cumulenes functionalized with heptagon-containing image polyphenylenes”

V. G. Jiménez, R. Tapia, M. A. Medel, I. F. A. Mariz, T. Ribeiro, V. Blanco, J. M. Cuerva, E. Maçôas and A. G. Campaña
Chem. Commun., 2018, 54, 3359-3362.

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2017


28) "Versatile synthesis and enlargement of functionalized distorted heptagon-containing nanographenes"

I. R. Márquez, N. Fuentes, C. M. Cruz, V. Puente-Muñoz, L. Sotorrios, M. L. Marcos, D. Choquesillo-Lazarte, B. Biel, L. Crovetto, E. Gómez-Bengoa, M. T. González, R. Martin, J. M. Cuerva and A. G. Campaña.
Chem. Sci., 2017, 8, 1068-1074. Article highlighted on Synfacts .
This article was selected among the Most Impactful Nanoscience Articles published in Chemical Science

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2014


27) "Ti/Ni-Mediated Inter and Intramolecular Conjugate Addition of Aryl and Alkenyl Halides and Triflates"

I. R. Márquez, D. Miguel, A. Millán, M. L. Marcos, L. Álvarez de Cienfuegos, A. G. Campaña and J. M. Cuerva.
J. Org. Chem., 2014, 79, 1529-1541. Article highlighted at “Featured Article”

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26) "Cp2TiCl-catalyzed highly stereoselective intramolecular epoxide allylation using allyl carbonates"

I. R. Márquez, A. Millán, A. G. Campaña and J. M. Cuerva.
Org. Chem. Front., 2014, 1, 373-381.

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25) "Recent applications of Cp2TiCl in natural product synthesis"

S. P. Morcillo, D. Miguel, A. G. Campaña, L. Álvarez de Cienfuegos, J. Justicia and J. M.Cuerva.
Org. Chem. Front. 2014, 1, 15-33.

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2013


24) "One Dimensional Random Walk of a Synthetic Small Molecule Towards a Thermodynamic Sink"

A. G. Campaña, D. A. Leigh and U. Lewandowska.
J. Am. Chem. Soc. 2013, 135, 8639-8645.

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23) "The Role of Water-Base Hydrogen Atom Wires in Long-Range Electron-Transfer Reactions in Aqueous Media for the Fe(II)-Fe(III) Self-Exchange and Related Systems"

A. G. Campaña, E. Buñuel, J. M. Cuerva and D. J. Cárdenas.
Chem. Eur. J. 2013, 19, 16187-16191.

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22) “DiChlorobis(cyclopentadienyl)titanium”

D. Miguel, A. G. Campaña, J. Justicia, J. M. Cuerva.
e-EROS: Encyclopedia of Reagents for Organic Synthesis, 2013.
DOI: 10.1002/047084289X.rd090m.pub2. (Book chapter)

2012


21) "Water Control over the Chemoselectivity of Ti/Ni Multimetallic system: Heck- or Reductive-Type Cyclization Reactions of Alkyl Iodides"

A. Millán, L. Álvarez de Cienfuegos, D. Miguel, A. G. Campaña, J. M. Cuerva.
Org. Lett. 2012, 14, 5984–5987

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20) “A Small Molecule that Walks Non-Directionally Along a Track Without External Intervention”

A. G. Campaña, A. Carlone, K. Chen, D. T. F. Dryden, D. A. Leigh, U. Lewandowska, K. M. Mullen.
Angew. Chem. Int. Ed. 2012, 51, 5480-5483.
This article has been featured on the INSIDE COVER of Angewandte Chemie, 22, 2012.

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19) "Ti/Ni Based Multimetallic System for the Efficient Allylation of Carbonyl Compounds”

A. Martínez-Peragón, A. Millán, A. G. Campaña, I. Rodríguez-Márquez, S. Resa, D. Miguel, L. Álvarez de Cienfuegos, J. M. Cuerva.
Eur. J. Org. Chem. 2012, 1499-1503.

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2011


18) “Light-driven transport of a molecular walker in either direction along a molecular track”

M. J. Barrell, A. G. Campaña, M. von Delius, E. M. Geertsema, D. A. Leigh
Angew. Chem. Int. Ed. 2011, 50, 285-290.
Featured on the FRONT COVER of the 50th Anniversary Volume of Angew. Chem. Int. Ed. 1, 2011.

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17) “Water-based Hydrogen-Atom Wires as Mediators in Long-Range Proton-Coupled Electron Transfer in Enzymes: a New Twist on Water Reactivity”

D. J. Cárdenas, J. M. Cuerva, M. Alias, E. Buñuel, A. G. Campaña
Chem. Eur. J. 2011, 17, 8318-8323.

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16) “Bioinspired terpene synthesis: a radical approach”

J. Justicia, L. Álvarez de Cienfuegos, A. G. Campaña, D. Miguel, V. Jakoby, A. Gansäuer, J. M. Cuerva
Chem. Soc. Rev. 2011, 40, 3525-3537.

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15) “Titanium/Palladium-Mediated Regioselective Propargylation of Ketones Using Propargylic Carbontates as Pronucleophiles”

A. Millán, L. Álvarez de Cienfuegos, A. Martín-Lasanta, A. G. Campaña, J. M. Cuerva
Adv. Synth. Catal. 2011, 353, 73-78.

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14) "Ti/Pd Bimetallic Systems for the Efficient Allylation of Carbonyl Compounds and Homocoupling reactions"

A. Millán, A. G. Campaña, B. Bazdi, D. Miguel, L. Álvarez de Cienfuegos, A. M. Echavarren, J. M. Cuerva
Chem. Eur. J. 2011, 16, 3985-3994.

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13) "Carbocations or Cyclopropyl Gold Carbenes in Cyclizations of Enynes"

P. Pérez-Galán, N. J. A. Martin, A. G. Campaña, D. J. Cárdenas, A. M. Echavarren.
Chem. Asian J. 2011, 16, 482-486.

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2010


12) "Understanding the Exceptional Hydrogen-Atom Donor Characteristics of Water in TiIII-Mediated Free-Radical Chemistry"

M. Paradas, A. G. Campaña, T. Jiménez, R. Robles, J. E. Oltra, E. Buñuel, J. Justicia, D. J. Cárdenas, J. M. Cuerva
J. Am. Chem. Soc. 2010, 132, 12748-12756.

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11) "Unprecedented H-atom transfer from water to ketyl radicals mediated by Cp2TiCl"

M. Paradas, A. G. Campaña, M. L. Marcos, J. Justicia, A. Haidour, R. Robles, D. J. Cárdenas, J. E. Oltra, J. M. Cuerva.
Dalton Trans. 2010, 39, 8796-8800.

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10) "Radical Reduction of Epoxides using a Titanocene(III)/Water System: Synthesis of β-Deuterated Alcohols and Their Use as Internal Standards in Food Analysis"

T. Jiménez, A. G. Campaña, B. Bazdi, M. Paradas, D. Arráez-Román, A. Segura-Carretero, A. Fernández-Gutiérrez, J. E. Oltra, R. Robles, J. Justicia, J. M. Cuerva.
Eur. J. Org. Chem. 2010, 4288-4295.

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2009


9) "Unexpected TiIII/Mn-Promoted Pinacol Coupling of Ketones"

M. Paradas, A. G. Campaña, R. E. Estévez, L. Álvarez de Cienfuegos, T. Jiménez, R. Robles, J. M. Cuerva, J. E. Oltra.
J. Org. Chem. 2009, 74, 3616-3619.

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2008


8) "Divergent titanium-mediated allylations with modulation by nickel or palladium"

A. G. Campaña, B. Bazdi, N. Fuentes, R. Robles, J. M. Cuerva, J. E. Oltra, S. Porcel, A. M. Echavarren.
Angew. Chem. Int. Ed. 2008, 47, 7515.

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7) "Titanium-Catalyzed Enantioselective Synthesis of α-Ambrinol"

J. Justicia, A. G. Campaña, B. Bazdi, R. Robles, J. M. Cuerva, J. E. Oltra.
Adv. Synth. Catal. 2008, 350, 571.

6) "SmI2-promoted intra- and intermolecular C-C bond formation with chiral N-acyl oxazolidinones"

R. H. Taaning, L. Thim, J. Karaffa, A. G. Campaña, A.-M. Hansen, T. Skrydstrup.
Tetrahedron 2008, 64, 11884.

2007


5) "Sodium Tetramethoxyborate: An Efficient Catalyst for Michael Additions of Stabilized Carbon Nucleophiles"

A. G. Campaña, N. Fuentes, E. Gómez-Bengoa, C. Mateo, J. E. Oltra, A. M. Echavarren, J. M. Cuerva.
J. Org. Chem. 2007, 72, 8127-8130.

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4) "Unprecedented Hydrogen Transfer from Water to Alkenes and Alkynes Mediated by TiIII and Late Transition Metals"

A. G. Campaña, R. E. Estévez, N. Fuentes, R. Robles, J. M. Cuerva, E. Buñuel, D. J. Cardenas, J. E. Oltra.
Org. Lett. 2007, 9, 2195.

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2006


3) "Water: The Ideal Hydrogen-Atom Source in Free-Radical Chemistry Mediated by Ti(III) and Other Single-Electron-Transfer Metals?"

J. M. Cuerva, A. G. Campaña, J. Justicia, A. Rosales, J. L. Oller-López, R. Robles, D. J. Cárdenas, E. Buñuel, J. E. Oltra.
Angew. Chem. Int. Ed., 2006, 45, 5522-5526.
Article awarded by the University of Granada in the 2009 Ed of the “Premios Universidad de Granada a Trabajos de Investigación de Excelencia”

03

2005


2) "7-endo Radical Cyclizations Catalyzed by Titanocene(III). Straightforward Synthesis of Terpenoids with Seven-membered Carbocycles"

J. Justicia, J. L. Oller-López, A. G. Campaña, J. E. Oltra, J. M. Cuerva, E. Buñuel, D. Cárdenas.
J. Am. Chem. Soc. 2005, 127, 14911-14921

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1) "Aromatic Carbonyl Compound Reduction and Pinacol Coupling Processes Mediated by Titanocene(III)/Zn in Water".

J. L. Oller-López, A. G. Campaña, J. M. Cuerva, J. E. Oltra.
Synthesis 2005, 2619- 2622